Download EBOOK Organolithiums: Selectivity for Synthesis PDF for free


Download EBOOK Organolithiums: Selectivity for Synthesis PDF for free Category: Science & Geography
The author of the book: Jonathan Clayden
Format files: PDF, EPUB, TXT, DOCX
The size of the: 6.85 MB
Language: English
ISBN-13: 9780080432618
Edition: Pergamon
Date of issue: 26 July 2002

Description of the book "Organolithiums: Selectivity for Synthesis":

This volume, number 23 in the "Tetrahedron Organic Chemistry" series, presents organolithium chemistry from the perspective of a synthetic organic chemist, drawing from the synthetic literature to present a unified overview of how organolithiums can be used to make molecules. The development of methods for the regioselective synthesis of organolithiums has replaced their image of indiscriminate high reactivity with one of controllable and subtle selectivity. Organolithium chemistry has a central role in the selective construction of C-C bonds in both simple and complex molecules, and for example has arguably overtaken aromatic electrophilic substitution as the most powerful method for PDF regioselective functionalisation of aromatic rings. The twin themes of reactivity and selectivity run through the book, which reviews the ways by which organolithiums may be formed and the ways in which they react. Topics include advances in directed metallation, reductive lithiation and organolithium cyclisation reactions, along with a discussion of organolithium stereochemistry and the role played by ligands such as (-)-sparteine.

Download EBOOK Organolithiums: Selectivity for Synthesis PDF for free


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Jonathan Clayden

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Download EBOOK Organolithiums: Selectivity for Synthesis PDF for free



Download EBOOK Organolithiums: Selectivity for Synthesis for free

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